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Based on the newly designed ligand 4′‐(3,5‐dicarboxyphenyl)‐4,2′:6′,4′′‐terpyridine (DCTP), a unique semi‐conductive 3D framework {[CuΙCuΙΙ2(DCTP)2]NO3⋅1.5 DMF}n (1) with a narrow band gap of 2.1 eV, was obtained and structurally characterized. DFT calculations with van de Waals correction employed to explore the electronic structure of 1, clearly revealed its semi‐conductive behavior. Furthermore,...
Metall‐organische Gerüstverbindungen mit zwei Arten photokatalytischer Aktivität auf der Grundlage von photogenerierten Elektronen und Löchern wurden bislang kaum untersucht. W.‐C. Wang, B. Zhao et al. beschreiben in der Zuschrift auf eine halbleitende Kupfer‐organische Gerüstverbindung mit einer schmalen Bandlücke von 2.1 eV. Nach theoretischen und experimentellen Befunden ist dieses Material ein...
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