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The atom transfer radical polymerization (ATRP) technique using the copper halide/sparteine complexes was applied to the graft polymerization of methyl methacrylate on a porous glass filter on which the initiator, 2-(4-chlorosulfonylphenyl) ethyltrichlorosilane, was immobilized by chemisorption. The graft chains were cleaved from the glass filter by the HF treatment in the presence of a phase transfer...
Monolayers of polymer blends composed of a rodlike polymer (tetra(methoxy)-tetra(octyloxy)-phthalocyaninato-polysiloxane (PcPS) or poly(γ-benzyl-L-glutamate)(PBLG)) and a flexible polymer (poly(isobutylvinyl ether)(PIBVE)) were studied by atomic force microscopy (AFM), transmission electron microscopy (TEM) and the surface pressure-area isotherm measurements. These blends were completely phase-separated...
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