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We trace pathways of Fe reactions in the Indian River Lagoon (Florida, USA) subterranean estuary using Fe isotopes to provide new constraints on Fe-isotopic fractionation in a sulfide-bearing subterranean estuary. Porewater δ 56 Fe values increase from −1.16‰ at 115cm depth to +0.2‰ at 7cm depth due to isotope fractionation in three distinct lithostratigraphic zones. The deepest zone contains...
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