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Schaltbare Katalyse in flexiblen MOFs, in diesem Fall der PCN‐700‐Serie, wird durch die inhärenten Hohlräume und das dynamische Verhalten Metall‐organischer Gerüstverbindungen ermöglicht. W. Lu, M. B. Hall, H.‐C. Zhou und Mitarbeiter zeigen in ihrer Zuschrift auf S. 10934 ff., dass die manuelle Steuerung der katalytischen Eigenschaften dieser MOFs, deren Eigenschaften und Verhalten stark an regulatorische...
Flexible metal–organic frameworks (MOFs) are highly desirable in host–guest chemistry owing to their almost unlimited structural/functional diversities and stimuli‐responsive pore architectures. Herein, we designed a flexible Zr‐MOF system, namely PCN‐700 series, for the realization of switchable catalysis in cycloaddition reactions of CO2 with epoxides. Their breathing behaviors were studied by successive...
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