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Plasmonic materials have drawn emerging interest, especially in nontraditional semiconductor nanostructures with earth‐abundant elements and low resistive loss. However, the actualization of highly efficient catalysis in plasmonic semiconductor nanostructures is still a challenge, owing to the presence of surface‐capping agents in their synthetic procedures. To fulfill this, a facile non‐aqueous procedure...
Die Verankerung kationischer Farbstoffmoleküle (Thiazolorange, TO) auf Pt‐TiO2 zur Bildung einer Sammeleinheit für sichtbares Licht gelang durch Modifikation der Pt‐TiO2‐Oberfläche mit 4‐Sulfocalix[4]aren als Linker, was Oberflächenkomplexe lieferte (siehe Bild). Dieses heterogene System ist ein effizienter Photokatalysator für die Wasserstofferzeugung in Gegenwart eines Opferreagens (TEOA=Triethanolamin).
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