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In this work, we studied the structural phase transformation and electrochemical characteristics of AB4-type La–Mg–Ni-based alloys through zoning annealing of La0.78Mg0.22Ni3.90 polymorphic alloy. The as-cast La0.78Mg0.22Ni3.90 alloy contained two phases of LaNi5 (50.8wt.%) and (La,Mg)2Ni7 (49.2wt.%). When annealed at 1173K, solid LaNi5 phase reacted with a liquid phase from (La,Mg)2Ni7 converting...
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