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Reactive spark plasma sintering (SPS) of WB2/WB3 ceramics from elements is studied; the sintering pressure dependence of the ratio of WB3 to WB2 in samples produced by SPS is discussed. Regardless of the sintering pressure, the obtained samples are very hard ~20GPa. WB3 superhard films prepared by pulsed laser deposition (PLD) from selected SPS targets are presented.WB3 coatings were prepared on Si...
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