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The heteroyclic ligand di-2-pyridyl ketone oxime (dpko) was reacted with MBr2·xH2O (M=Cu, Zn), affording several novel complexes. [Cu2(dpko)2Br4][CuBr4] and Zn(dpko)Br2 complexes are analogs of previously reported chloride complexes, and both are structurally and spectroscopically similar to the chloride analogs, [Cu2(dpko)2Cl4]Cl2 and Zn(dpko)Cl2; however, [Cu2(dpko)2Br4][CuBr4] crystallizes as the...
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