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Glycosphingolipids isolated from larvae of the green-bottle fly, Lucilia caesar, have quite unique structures containing GlcNAcβ-(1->3)-Man and GalNAcβ-(1->4)-GlcNAcβ-(1->3)-Man. We have synthesized two glycosphingolipids, β-d-GlcNAcp-(1->3)-β-d-Manp-(1->4)-β-d-Glcp-(1->1)-Cer and β-d-GalNAcp-(1->4)-β-d-GlcNAcp-(1->3)-β-d-Manp-(1->4)-β-d-Glcp-(1->1)-Ce r. A key reaction...
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