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We report evidence of the favorable noncovalent interaction between a covalently bonded atom of Group 18 (known as noble gases or aerogens) and a negative site, for example, a lone pair of a Lewis base or an anion. It involves a region of positive electrostatic potential (σ‐hole), therefore it is a totally new and unexplored σ‐hole‐based interaction, namely aerogen bonding. We demonstrate for the...
Im Loch: Eine Tetrelbindung ist eine gerichtete nichtkovalente Wechselwirkung zwischen einem kovalent gebundenen Gruppe‐IV‐Atom und einem negativ geladenen Zentrum, etwa einem freien Elektronenpaar einer Lewis‐Base oder einem Anion. Tetrelbindungen umfassen einen Bereich positiven elektrostatischen Potentials (σ‐Loch) und sind aus energetischer Sicht mit Wasserstoffbrücken und anderen auf σ‐Löchern...
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