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Intramolecular long-range electron transfer (LRET) in hen egg-white lysozyme (HEWL) accompanying Trp → TyrO radical transformation was investigated in aqueous solution by pulse radiolysis as a function of pH (5.2-7.4) and temperature (283-328 K). The reaction was induced by highly selective oxidation of Trp with N 3 radicals under low concentration of the reactants but at a high HEWL/N ...
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