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The reaction of the monofunctional [Pt(Gly-Gly-N,N′,O)I] − complex, in which Gly-Gly is the dipeptide glycyl-glycine coordinated through two nitrogen and oxygen atoms, with the N-acetylated dipeptide l-methionyl-l-histidine (MeCOMet-His) studied by 1 H NMR spectroscopy. All reactions were carried out in 50mM phosphate buffer at pD 7.4 and at 25°C. In the initial stage of the reaction,...
1 H NMR spectroscopy was applied to study the reactions of palladium(II) complexes, cis-[Pd(dpa)Cl 2 ] and cis-[Pd(dpa)(H 2 O) 2 ] 2+ (dpa is 2,2′-dipyridylamine acting as a bidentate ligand) with the dipeptides methionylglycine (Met-Gly) and histidylglycine (His-Gly), and the N-acetylated derivatives of these dipeptides, MeCOMet-Gly and MeCOHis-Gly. All reactions...
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