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To elucidate the chemical structure ofp-hydroxycinnamyl aldehyde moieties of abnormal angiosperm lignins of cinnamyl alcohol dehydrogenase down-regulated plants, sinapyl and coniferyl aldehydes were subjected to thioacidolysis. and the products were analyzed by gas chromatograph-mass spectrometer (GC-MS). The chromatograms indicated that two pairs of new isomeric compounds were released during thioacidolysis...
The enzymatically dehydrogenative polymerization of coniferyl aldehyde and coniferyl alcohol was studied to understand lignins in cinnamyl alcohol dehydrogenase (CAD)-downregulated plants. The sample dimers were prepared by polymerization under three reaction systems (coniferyl alcohol, coniferyl aldehyde, and their combination) with horseradish peroxidase/H2O2 under the conditions of limited reaction...
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