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A supramolecular crystal, guanidinium-3,5-dinitrobenzoate (GDNB), was synthesised and its structure was confirmed by single crystal X-ray diffraction at 25 °C. Distinct NH⋯O hydrogen bonding interactions as well as π-π interactions in GDNB were ascertained from the crystal structure. An exhaustive Hirshfeld surface analysis spells out variety of intermolecular contacts in GDNB proving the existence...
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