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Hierarchical metal‐organic frameworks with low‐dimensional architectures provide significant thermodynamic or kinetic benefits. Yiyun Geng, Gang Ye et al. present in their Research Article (e202312697) the development of nanosheet‐assembled Zr‐porphyrin frameworks with broadband photon harvesting and enhanced photocatalytic ability, enabling the establishment of an initiator‐free, visible‐light‐regulated...
Metal–organic frameworks with well‐organized low‐dimensional architectures provide significant thermodynamic and/or kinetic benefits for diverse applications. We present here the controlled synthesis of a novel class of hierarchical zirconium‐porphyrin frameworks (ZrPHPs) with nanosheet‐assembled hexagonal prism morphology. The crystal growth behaviors and structural evolution of ZrPHPs in an additive‐modulated...
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