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New poly(cobaltacyclopentadienylene)s with π-conjugated spacers were synthesized by metallacycling polymerization (MCP) using CpCo(PPh 3 ) 2 (Cp = η 5 -cyclopentadienyl) and Me-C=C-A-C=C-Me, where A = phenylene and thienylene, as starting materials. The number-average molecular weights of polymers were 3.8x10 5 (M w /M n = 4.5) and 4.4x10 3 (M...
An iron cyclopentadienyl complex of a conducting polymer, poly (n-hexylphenylene) (abbreviated as PHP), was prepared by a reaction of PHP with ferrocene, Al and AlCl 3 followed by an anion exchange using NH 4 PF 6 . Cyclic voltammetry of the complex thus formed with a formula, {(C 6 H 3 C 6 H 13 ) 1.6 [ (η 6 -C...
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