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Chiral Pybox–Ru catalysts can be microencapsulated into linear polystyrene as a method to recover and recycle the valuable catalyst. These catalysts allow 60–68% yields to be achieved with enantioselectivities in the range 75–85% ee in the benchmark cyclopropanation reaction between styrene and ethyl diazoacetate. The catalyst is soluble in the reaction solvent and is re-encapsulated at the end of...
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