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Aqueous soluble and stable Cu(I) molecular catalysts featuring a catenane ligand composed of two dicationic, mutually repelling but mechanically interlocked macrocycles are reported. The ligand interlocking not only fine‐tunes the coordination sphere and kinetically stabilizes the Cu(I) against air oxidation and disproportionation, but also buries the hydrophobic portions of the ligands and prevents...
Herein, we report high‐performance fuel cells that are catalyzed solely by polyoxometalate (POM) solution without any solid metal or metal oxide. The novel design of the liquid‐catalyst fuel cells (LCFC) changes the traditional gas–solid‐surface heterogeneous reactions to liquid‐catalysis reactions. With this design, raw biomasses, such as cellulose, starch, and even grass or wood powders can be directly...
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