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Myoglobin (Mb) in thin films of phosphatidyl cholines (PC) or dihexadecyl phosphate (DHP) gave direct, reversible electron transfer between pyrolytic graphite electrodes and the heme Fe(III)/Fe(II) redox couple of the protein. PC films incorporated much more Mb than DHP films. A model assuming several classes of electroactive sites in the films on the electrode with a dispersion of standard potentials...
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