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Ti-rich Ti 45 Zr 5 Cu 45 Ni 5 bulk metallic glass with critical diameter reaching 3mm and supercooled liquid region of 42K was prepared by copper mold casting. The glass transition temperature and onset temperature of crystallization are 673K and 715K, respectively. The glassy Ti–Zr–Cu–Ni alloy is passive in 3mass% NaCl, 1N HCl and 1N H 2 SO 4 solutions,...
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