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A zinc bacteriochlorophyll-d analog possessing a fully π-conjugated porphyrin skeleton and an acrylate residue at the 17-position was prepared by chemical modification of an accessory photosynthetic pigment, chlorophyll-c1 from a diatom Chaetoceros species. The synthetic zinc chlorophyll-c1 derivative self-aggregated in a less polar organic solvent and in a solid film to give a red-shifted and broadened...
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