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The new complexes of 5-methoxyindole-2-carboxylic acid (5-MeOI2CAH) and indole-2-carboxylic acid (I2CAH) with manganese(II): catena-poly[diaquamanganese(II)-bis(μ2-5-methoxyindole-2-carboxylato-O:O′)], [Mn(5-MeOI2CA)2(H2O)2]n (1) and catena-poly[diaquamanganese(II)-bis(μ2-indole-2-carboxylato-O:O′)], [Mn(I2CA)2(H2O)2]n (2) have been prepared. A single crystal X-ray analysis of 1 shows that the complex...
The crystal and molecular structures of indole-2-carboxylic acid (ICA) have been determined using single crystal X-ray diffraction, infrared spectroscopy and theoretical methods.The crystals are orthorhombic, space group Pna2 1 , with a=30.144(6)A, b=6.466(1)A, c=3.819(1)A, V=744.4(3)A 3 and z=2. The structure analysis revealed that two chains of ICA molecules form a planar ribbon,...
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