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The copolymerization of zirconium oxo‐clusters (Zr12) with 3‐methacryloxypropyl (trimethoxy)silane (MPTMS), using a Si/Zr molar ratio of 4, was investigated. The hybrid samples were prepared both with and without organosilane prehydrolysis. Differential scanning calorimetry (DSC), multinuclear liquid, and solid state NMR analyses and Fourier transform infrared (FTIR) spectroscopy were used to characterize...
Various Nano Building Blocks (NBBs) such as polyhedral silsesquioxanes (POSS), functionalized metal oxide particles and transition metal oxoclusters have been already developed and used to improve thermal and mechanical properties of organic polymers. The NBBs ideal for the preparation of hybrid materials and nanocomposites are monodispersed, well-defined objects capped with polymerisable functions...
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