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The 2‐thiomethylbenzofuran derivatives 3 are conveniently prepared in good yields through the reactions between the readily available 2‐methylene‐2,3‐dihydrobenzofuran‐3‐ols 1 and the thiol derivatives 2 (including alkyl thiols, thiophenol, and thioacetic acid). The allylic substitution process may be either acid‐catalysed or promoted by radical initiators. In the first case, the reactions are carried...
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