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Developing K‐ion conducting solid‐state electrolytes (SSEs) plays a critical role in the safe implementation of potassium batteries. In this work, a chalcogenide‐based potassium ion SSE is reported, K3SbSe4, which adopts a trigonal structure at room temperature. Single‐crystal structural analysis reveals a trigonal‐to‐cubic phase transition at the low temperature of 50 °C, which is the lowest among...
A lanthanide cluster, PCC‐72, which is the second largest, with 72 Dy(III) ions assembled into an unprecedented tubular structure, is synthesized. Remarkably, PCC‐72 exhibits superionic proton conductivity (>10−4 S cm−1) under both ambient (with relative humidity RH < 75%) and hot (T > 90 °C, RH = 95%) conditions. Moreover, slow magnetic relaxation is observed, making PCC‐72 the largest Dy(III)...
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