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Our group has developed a series of molecular electrocatalysts for hydrogen generation based on triazenido–metal complexes (cobalt, copper, etc.). In this paper, we first present the electrocatalytic performance of a new dinuclear silver complex, [Ag2(L)2], formed by the reaction of the triazenido ligand 1‐[(2‐carboxymethyl)benzene]‐3‐[(2‐methoxy)benzene]triazene (HL) with AgNO3. At room temperature,...
A new molecular catalyst based on a tetra-nuclear copper(I), [CuI4(L)4] 1 is prepared by the reaction of the triazenido ligand, [1,3-bis(2-methoxy)benzene]triazene (HL) with CuCl. X-ray structural studies show that four copper atoms are triazenido-bridged with four independent Cu⋯Cu distances of 2.5881(7)–2.6048(7)Å. Complex 1 can act as an electrocatalyst for hydrogen generation with 170.66mol of...
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