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The usefulness of Keggin-type anions (PMo 12 O 403− ) as both reducing, capping and activating agents during synthesis of polyoxometallate-modified gold nanoparticles is demonstrated here. Fabrication of gold nanoparticles stabilized with monolayer-type films of inorganic polyoxometallates (e.g. phosphododecamolybdates), Au-PMo 12 , was achieved by treating an aqueous...
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