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Phase relationship analysis in the pseudobinary SmBaCo 2−x Cu x O 6−δ system at 1000–1100°С in air revealed the existence of solid solutions with the layered perovskite and 123-type structures, formed within the ranges of 0≤x≤1.2 and 1.5≤x≤2.0, respectively. The substitution of Cu 2+ for Co 3+/4+ was found to induce phase transition from orthorhombic (space...
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