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Five-coordinate thiolato complexes, [L1M(SMeIm)] (M=Co and Ni) (L1=hydrotris(3,5-diisopropyl-1-pyrazolyl)borate anion and HSMeIm=2-mercapto-1-methylimidazole), were synthesized. These complexes were compared with the corresponding Cu(II) and Zn(II) complexes with the same ligands and were also compared with the related four-coordinate complexes [L1M(SC 6 F 5 )] (HSC 6 F ...
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