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The half-Heusler (HH) systems are promising candidates for thermoelectric (TE) applications since they have shown high figures of merit (zT) of $$\sim $$ ∼ 1, which are directly related to the energy conversion efficiency. To use HH compounds for TE devices, the materials must be phase-stable at operating temperatures up to $$600^{\circ }$$ 600 ∘ C. Currently, only a few HH compositions...
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