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Effects of lattice and polar/nonpolar mismatch between the GaP layer and Ge(111) substrate are investigated by spatially resolved Raman spectroscopy. The red shifted transverse optical (TO) and longitudinal optical (LO) phonons due to residual strain, along with asymmetry to TO phonon ∼358cm−1 are observed in GaP/Ge(111). The peak intensity variation of mode ∼358cm−1 with respect to TO phonon across...
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