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Piezoelectric 3–3 composites are often prepared from unpoled PZT ceramics and polymer matrices. During the poling process the PZT cannot deform freely due to the clamping by the surrounding polymer, which after poling results in the occurrence of residual mechanical stress in the composite. Based on the multi-linear constitutive model of ferroelectric and ferroelastic piezoceramics, a nonlinear finite...
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