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A zinc porphyrin dimer assembles to give a sandwich complex in the presence of 1equiv. of the bidentate ligand DABCO. The effective molarity for cyclisation is 2mM, so that the macrocyclic sandwich complex can be studied at μM concentrations by UV/Vis absorption spectroscopy, but at NMR concentrations, insoluble polymeric assemblies are formed. The potential of this system to function as a molecular...
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