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In the time-resolved flash photolysis of I 2 in O 3 , in addition to the IO electronic bands between 21500 and 26000 cm -1 , a new absorption spectrum has been observed between 15000 and 21500 cm -1 , which is attributed to the A-X electronic bands of the OIO radical. A number of spectroscopic constants of the A state of OIO were determined by linear least-squares...
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