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Profound understanding of relationships between molecular networks with properties can make it more convenient for people to prepare and employ shape memory polymers (SMPs). In this paper, a series of epoxy SMPs were developed based on epoxy (E‐51), trimethylolpropane tris(3‐mercaptopropionate) and pentaerythritoltetrakis (3‐mercaptopropionate), and 2‐methylimidazole, through “epoxy‐thiol” click reaction...
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