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Nimm fünf: Ein einzigartiger, fünffach gebundener Dimolybdän‐Komplex [Mo2(μ‐Li){μ‐HC(N‐2,6‐Et2C6H3)2}3] (siehe Bild) wurde synthetisiert und charakterisiert. Die Mo‐Mo‐Wechselwirkung schließt ein unerwartetes verbrückendes Li+‐Ion mit ein. Berechnungen zeigen, dass das verbrückende Li+‐Ion die Mo‐Mo‐Bindungslänge nicht beeinflusst (2.0612(4) Å), aber eine relativ kleine effektive Mo‐Mo‐Bindungsordnung...
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