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The influence of vinylidenefluoride (3% composition) on the physical ageing of poly(chlorotrifluoroethylene) at 70 o C has been investigated using the positron annihilation lifetime technique. Both the ortho-positronium (o-Ps) pick-off lifetime and its intensity show a systematic variation with ageing time. The o-Ps intensity exhibits non-exponential character which can be fitted with two...
The influence of vinylidenefluoride (three different compositions, viz. 0, 0.5 and 3.0%) on the free volume of the polymer poly(chlorotrifluoroethylene) has been investigated using the Positron Annihilation Lifetime technique. The lifetime results indicate that, with the increase in the composition of vinylidenefluoride, the average free volume size of the polymer decreases whereas their number density...
The effect of stress (hydrostatic compression) on the free volume of poly(chlorotrifluoroethylene) has been investigated using the position annihilation lifetime (PAL) technique in the pressure range of 0-14 kbar at room temperature. The variation of the annihilation parameters indicates that the free volume compression occurs at a higher pressure (>8 kbar) compared to molecular compression (4...
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