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The emulsifier-free emulsion polymerization of vinyl acetate (VAc) and butyl acrylate (BA) in the presence of 2-acrylamido-2-methylpropane sulfonic acid (AMPS) was carried out by a semi-continuous process. AMPS was a reactive surfactant in the aqueous emulsion, due to its amphiphilic structure and the unsaturated double bonds. Potassium persulfate (KPS) was used as initiator. The following factors...
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