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Molecules with furanose units are often bioactive. To concisely synthesize these molecules, we have developed aldol reactions of 1,2-diketones that afford furanose derivatives in one pot. For these reactions with the use of N,N′-diisopropylethylamine as catalyst, aldol products were obtained via C–C bond formation at the internal methylene carbon of the acetyl alkyl ketone derivatives. Regioselectivities...
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