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Background: Trihydroxynaphthalene reductase catalyzes two intermediate steps in the fungal melanin biosynthetic pathway. The enzyme, a typical short-chain dehydrogenase, is the biochemical target of three commercial fungicides. The fungicides bind preferentially to the NADPH form of the enzyme.Results: Three X-ray structures of the Magnaporthe grisea enzyme complexed with NADPH and two commercial...
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