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Bicarbonate anion (HCO3−) is a major constituent in wastewater and natural water matrices, and the aim of this study was to investigate its roles in the degradation of the antineoplastic agent methotrexate via UV/TiO2. A comprehensive investigation of reaction mechanisms was performed by conducting scavenger experiments and substructure reactivity and Microtox® toxicity tests. In the presence of HCO...
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