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A series of N-base appended corroles and their manganese complexes were synthesized and their binding constants with three different nitrogenous ligands, triethylamine, N-methylimidazole and pyridine, were evaluated by spectroscopy. Kinetic studies indicated that the presence of appended N-donor ligands may cause a significant enhancement of the rate of oxygen atom transfers (OAT) from (oxo)manganese(V)...
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