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The valuable 2-(tert-butyldisulfanyl)heterocycles were effectively synthesized from 2-mercaptoheterocycles and tert-butanesulfinamide via unusual condensation. The reaction between 2-mercapto sulfur-containing heterocycles and tert-butanesulfinamide was performed under ligand-free CuI-catalyzed conditions. The synthetic processes described herein are simple, cost-efficient, and practical. Furthermore,...
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