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Anodizing of sputtering-deposited Al–Mg alloys containing 27 and 32at.% magnesium in sodium hydroxide electrolyte is shown to develop two-layered anodic oxide films. The outer layer contains aluminium and magnesium species, and is enriched in the latter species relative to the alloy, particularly towards the film surface. The inner layer also contains the two alloy species but is depleted in magnesium,...
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