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Metal carbonyl thionitrosyls are potentially accessible by reactions of metal carbonyl anions and related nucleophiles with N 3 S 3 Cl 3 as illustrated by the reported synthesis of (η 5 -C 5 H 5 )Cr(NS)(CO) 2 from N 3 S 3 Cl 3 and NaCr(CO) 3 (η 5 -C 5 H 5 ). Related manganese carbonyl thionitrosyls...
An important recent development in metal disulfide chemistry is the 2001 synthesis by Adams et al. of Mn 2 S 2 (μ-CO)(CO) 6 containing both a bridging disulfide ligand and a bridging carbonyl group. During the ensuing decade this manganese complex has proven to be a key intermediate for the synthesis of diverse manganese carbonyl sulfur derivatives, including heterometallic...
The turbid removal experiments were conducted with hydrated manganese dioxide that produced by deoxidization of KMnO4 for simulated water and Tiansha River water. And the factors that influence the coagulation and the effects of coagulation were analyzed in this study. The results showed that hydrated manganese dioxide was one kind of effective water treatment agent which has significant removal effect...
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