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The mechanism for the Cl-initiated oxidation of ethyl formate (EF) has been determined in the presence of NO 2 . The Cl atom initiates the oxidation mainly at two different sites of the molecule; one corresponds to the H-atom abstraction on the carbon atom in the α-position of the oxygenated carbonylic group (62±7)% and the second to the H-atom on the carbonylic group (44±5)%. The quantification...
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