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First-principles investigation of the Heusler compounds Cr 2 VX (X=Ga, Si, Ge, Sb) revealed that the Cr 2 VSb exhibits a half-metallic nature yet Cr 2 VSi and Cr 2 VGe show nearly half-metallic ferromagnetism. Their band structures show a striking difference between the majority and minority spin directions. The Cr–V covalence bonding strength increases in the Ga→Si→Sb...
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