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1,2-Dimethyl-3-(1′,1′,3′,3′-tetramethyl-3′-phenyldisiloxanyl)methylimidazolium bis(trifluoromethanesulfonyl)amide ([PhC5OSi2MMIm+][Tf2N−]) is the first silicon-containing ionic liquid which was characterized with the vaporization enthalpy, (138.5±1.8)kJmol−1, and saturated vapor pressure, ln(p/Pa)=−(16656±219)/(T/K)+(30.69±0.92). This compound is a unique ionic liquid giving ions, retaining both cationic...
An efficient method for the diastereoselective synthesis of 5-substituted 3,4-fulleroproline esters based on the lithium salt-assisted cycloaddition of azomethine ylides has been developed. A series of the fulleroproline esters containing either electron donating or electron withdrawing substituents was prepared with high yields and diastereoselectivities provided by the S-trans-configuration of ylide...
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