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The thermodynamic description of Li containing systems is readily accessible by coulometric titrations in combination with EMF measurements. Although this method is often encountered in literature, the experimental apparatus needed is in general only poorly described. As Li and its alloys are very reactive substances, many parameters like the materials used for the electrochemical cell, cell geometry,...
The partial and integral enthalpies of mixing of liquid ternary Ni–Sb–Sn alloys were determined along five sections x Sb /x Sn =3:1, x Sb /x Sn =1:1, x Sb /x Sn =1:3, x Ni /x Sn =1:4, and x Ni /x Sb =1:4 at 1000°C in a large compositional range using drop calorimetry techniques. The mixing enthalpy of Ni–Sb alloys was...
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