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Substitution of liquid electrolyte with solid‐state electrolytes (SSEs) has emerged as a very urgent and challenging research area of rechargeable batteries. NASICON (Na3Zr2Si2PO12) is one of the most potential SSEs for Na‐ion batteries due to its high ionic conductivity and low thermal expansion. It is proven that the ionic conductivity of NASICON can be improved to 10−3 S cm−1 by Sc‐doping, of which...
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